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Bimetallic AuPt alloy nanodendrites/reduced graphene oxide: One-pot ionic liquid-assisted synthesis and excellent electrocatalysis towards hydrogen evolution and methanol oxidation reactions

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Abstract Herein, reduced graphene oxide supported well-dispersed bimetallic AuPt alloy nanodendrites (AuPt ANDs/rGO) were fabricated by a one-pot coreduction approach using ionic liquid (1-aminopropyl-3-methylimidazolium bromide, [APMIm]Br) as the stabilizer and… Click to show full abstract

Abstract Herein, reduced graphene oxide supported well-dispersed bimetallic AuPt alloy nanodendrites (AuPt ANDs/rGO) were fabricated by a one-pot coreduction approach using ionic liquid (1-aminopropyl-3-methylimidazolium bromide, [APMIm]Br) as the stabilizer and capping agent. There is no any other polymer or seed involved. Characterized measurements include transmission electron microscopy (TEM), high angle annular dark-field scanning TEM (HAADF-STEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The typical samples displayed excellent electrocatalytic activity and durability towards hydrogen evolution reaction (HER) and methanol oxidation reaction (MOR) in contrast with Pt nanocrystals/rGO and commercial Pt/C (50%) catalysts, which make it promising for practical catalysis in energy conversion and storage.

Keywords: graphene oxide; hydrogen; aupt alloy; reduced graphene; bimetallic aupt; alloy nanodendrites

Journal Title: International Journal of Hydrogen Energy
Year Published: 2017

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