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Synthesis of multi-functional epoxides derived from limonene oxide and its application to the network polymers

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Abstract Bio-based multi-functional epoxides ( 1 ) such as bis-, tri-, and tetra-epoxides were synthesized by ene-thiol reactions between limonene oxide and polyhydric thiols. A cross-linking reaction of 1 with… Click to show full abstract

Abstract Bio-based multi-functional epoxides ( 1 ) such as bis-, tri-, and tetra-epoxides were synthesized by ene-thiol reactions between limonene oxide and polyhydric thiols. A cross-linking reaction of 1 with branched polyethyleneimine (BPEI) afforded the corresponding network polymers 2 with relatively high thermal resistance in high yields.

Keywords: network polymers; limonene oxide; multi functional; synthesis multi; functional epoxides

Journal Title: Tetrahedron Letters
Year Published: 2017

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