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Crystal structure of new triple molybdate AgMg3Ga(MoO4)5 from Rietveld refinement

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A polycrystalline sample of a new triple molybdate AgMg3Ga(MoO4)5 was obtained by solid-state reaction techniques. Structural refinement based on X-ray powder diffraction data showed that the crystal structure is isotypic… Click to show full abstract

A polycrystalline sample of a new triple molybdate AgMg3Ga(MoO4)5 was obtained by solid-state reaction techniques. Structural refinement based on X-ray powder diffraction data showed that the crystal structure is isotypic with NaMg3In(MoO4)5 (sp. gr. P $\bar 1$ ). In the structure pairs of edge-shared (Mg, Ga)O6, octahedra are connected by common vertices to form a three-dimensional framework. Large framework cavities involve Ag+ cations. The title compound was found to melt at 1079 K.

Keywords: crystal structure; molybdate agmg3ga; triple molybdate; agmg3ga moo4; new triple; structure

Journal Title: Powder Diffraction
Year Published: 2017

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