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Chemistry of 4-[(4-bromophenyl)ethynyl]pyridine at metal surfaces studied by STM.

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Molecular architectures (Kagome networks, coordinated/covalent dimers and branched coordination chains) via self-assembly, Ullmann reaction and pyridine coordination of 4-[(4-bromophenyl)ethynyl]pyridine are found to be sensitive to the underlying metallic surfaces. The… Click to show full abstract

Molecular architectures (Kagome networks, coordinated/covalent dimers and branched coordination chains) via self-assembly, Ullmann reaction and pyridine coordination of 4-[(4-bromophenyl)ethynyl]pyridine are found to be sensitive to the underlying metallic surfaces. The molecular species were characterised on the surface by low-temperature scanning tunnelling microscopy (LT-STM) at sub-molecular level.

Keywords: pyridine; bromophenyl ethynyl; chemistry bromophenyl; chemistry; ethynyl pyridine; pyridine metal

Journal Title: Chemical communications
Year Published: 2018

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