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Ferroelastic phase transition and the role of volume strain in the structural trapping of a metastable quenched low-spin high-symmetry phase in [Ru0.35Fe0.65(ptz)6](BF4)2

Spin-crossover (SCO) materials exhibit thermal conversion of their electronic state from low (LS) to high (HS) spin state, which also involves both intra- and inter-molecular structural reorganisations within the crystal.... Click to show full abstract

Spin-crossover (SCO) materials exhibit thermal conversion of their electronic state from low (LS) to high (HS) spin state, which also involves both intra- and inter-molecular structural reorganisations within the crystal....

Keywords: role volume; ferroelastic phase; transition role; phase transition; phase; volume strain

Journal Title: CrystEngComm
Year Published: 2023

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