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Titanium-catalysed deoxygenation of benzylic alcohols and lignin model compounds

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We report a catalytic system for direct deoxygenation of benzylic alcohols by using non-precious precatalyst Cp2TiCl2 and 2 MeTHF as solvent. Mechanistic studies showed that the used silane Me(EtO)2SiH acts... Click to show full abstract

We report a catalytic system for direct deoxygenation of benzylic alcohols by using non-precious precatalyst Cp2TiCl2 and 2 MeTHF as solvent. Mechanistic studies showed that the used silane Me(EtO)2SiH acts...

Keywords: catalysed deoxygenation; benzylic alcohols; titanium catalysed; deoxygenation benzylic

Journal Title: Organic Chemistry Frontiers
Year Published: 2023

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