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Sm(II)-mediated Single-electron Reduction of Pentafluorophenylcopper(I)

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The single-electron-transfer reduction of pentafluorophenylcopper(I) using the Sm(II) reagents SmI2 and Cp*2Sm (Cp* = pentamethylcyclopentadienyl) resulted in the formation of ion-paired [Sm(II)]+[... Click to show full abstract

The single-electron-transfer reduction of pentafluorophenylcopper(I) using the Sm(II) reagents SmI2 and Cp*2Sm (Cp* = pentamethylcyclopentadienyl) resulted in the formation of ion-paired [Sm(II)]+[...

Keywords: electron reduction; single electron; reduction pentafluorophenylcopper; mediated single

Journal Title: Chemistry Letters
Year Published: 2021

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