Metal-Free Generation of γ-Cyanoalkyl Radicals by N-Heterocyclic Carbene Catalysis: Assembly of 6-Cyanoalkyl Phenanthridines.
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DOI: 10.1021/acs.orglett.2c03808
Abstract: A number of γ-cyanoalkyl radicals were generated by sustainable N-heterocyclic carbene catalysis in tin-, transition-meal-, and light-free conditions, followed by insertion into biaryl isonitriles, thus leading to the rapid assembly of a variety of diversely… read more here.
Keywords: cyanoalkyl radicals; cyanoalkyl phenanthridines; cyanoalkyl; heterocyclic carbene ... See more keywords