Photo-induced energy transfer mediated O2-initiated deboronative generation of alkyl radicals from alkyl boronic acids and its application in radical Smiles rearrangement
Sign Up to like & getrecommendations! Published in 2025 at "Organic Chemistry Frontiers"
DOI: 10.1039/d5qo00323g
Abstract: A visible-light-induced, energy-transfer mechanism for O2-initiated deboronative generation of alkyl radical approaches from alkylboronic acids and guided to a Smiles rearrangement reaction has been developed. This protocol utilizes tetracoordinate boron... read more here.
Keywords: deboronative generation; induced energy; initiated deboronative; energy transfer ... See more keywords