Modular access to substituted germoles by intramolecular germylzincation.
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DOI: 10.1039/d1cc07163g
Abstract: Intramolecular alkyne germylzincation giving access to a wide range of germoles is achieved from triarylhydrogermanes in the presence of diethylzinc and AIBN as radical initiator. The reaction proceeds through activation of the Ge-H bond, leading… read more here.
Keywords: germylzincation; modular access; access substituted; substituted germoles ... See more keywords
Modular access to substituted cyclohexanes with kinetic stereocontrol
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DOI: 10.1126/science.abn9124
Abstract: Substituted six-membered cyclic hydrocarbons are common constituents of biologically active compounds. Although methods for the synthesis of thermodynamically favored, disubstituted cyclohexanes are well established, a reliable and modular protocol for the synthesis of their stereoisomers… read more here.
Keywords: access substituted; kinetic stereocontrol; disubstituted cyclohexanes; modular access ... See more keywords