Slow magnetic relaxation in mononuclear octa-coordinate Fe(II) and Co(II) complexes from a Bpybox ligand.
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DOI: 10.1039/d2dt00865c
Abstract: Two 3d transition metal mononuclear complexes, [(FeL2)(ClO4)2]2·CH3CN (1) and (CoL2)(ClO4)2·2CH3CN (2), have been prepared from a rigid tetradentate bpybox (L = 6,6'-bis(2,5-dihydrooxazol-4-yl)-2,2'-bipyridine) ligand. Single crystal X-ray diffraction analyses together with the help of calculations show… read more here.
Keywords: mononuclear; magnetic relaxation; octa coordinate; relaxation ... See more keywords