Facile preparation of pyrimidinediones and thioacrylamides via reductive functionalization of amides.
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DOI: 10.1039/c7cc04170e
Abstract: The development of an efficient protocol for the reductive functionalization of amides into pyrimidinediones and amino-substituted thioacrylamides is presented. Enamines are generated in a highly chemoselective amide hydrosilylation reaction catalyzed by molybdenum hexacarbonyl in combination… read more here.
Keywords: functionalization amides; preparation pyrimidinediones; reductive functionalization; facile preparation ... See more keywords