H/F Substitution induced switchable coordination bonds in a cyano-bridged hybrid double perovskite ferroelastic.
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DOI: 10.1039/d2cc00586g
Abstract: A three-dimensional cyano-bridged double perovskite ferroelastic [(CH3)3NCH2F]2[KFe(CN)6] was constructed by introducing unprecedented switchable C-F-K coordination bonds. H/F substitution not only preserves the basic structure of the parent [(CH3)4N]2[KFe(CN)6] but also affords an m3̄mF2/m-type ferroelastic phase… read more here.
Keywords: perovskite ferroelastic; cyano bridged; switchable coordination; coordination bonds ... See more keywords