Reactions of [Os3(CO)10(μ-dppm)] and [HOs3(CO)8{μ3-Ph2PCH2P(Ph)C6H4}] with Bu3GeH: Ge–H and Ge–C bond cleavage at triosmium centers
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DOI: 10.1016/j.jorganchem.2019.07.013
Abstract: Abstract The reactivity of the triosmium clusters [Os 3 (CO) 10 (μ-dppm)] [dppm = bis(diphenylphosphino)methane] and [HOs 3 (CO) 8 {μ 3 -Ph 2 PCH 2 P(Ph)C 6 H 4 }] with tributylgermanium hydride (Bu 3 GeH)… read more here.
Keywords: pch; os3 dppm; geh; reactions os3 ... See more keywords
Facile Os-Os bond cleavage in the reactions of [Os3(CO)10(NCMe)2] and [Os3(CO)10(μ-H)2] with tetramethylthiuram disulfide (tmtd): Syntheses and crystal structures of new polynuclear osmium carbonyl complexes containing a dimethyldithiocarbamate ligand(s)
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DOI: 10.1016/j.jorganchem.2020.121133
Abstract: Abstract The reaction of the labile triosmium cluster [Os3(CO)10(NCMe)2] with tetramethylthiuram disulfide [(Me2NCS2)2, tmtd] has been investigated at room temperature. Conducting the reaction under mild conditions has permitted the isolation of the three new polynuclear… read more here.
Keywords: osmium; tetramethylthiuram disulfide; os3 ncme; new polynuclear ... See more keywords