Controlled Assembly of Ru-Containing Polyoxometalates for Photocatalytic Activity of the Primary Amine Coupling Reaction.
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DOI: 10.1021/acs.inorgchem.2c00718
Abstract: Three Ru-induced structural interconversion polyoxometalates (POMs), Na13H5[Ru4(H2O)2(Cl)2(WO2)4(AsW9O33)4]·43H2O (1), K5Na9H8[Ru2(WO2)4(AsW9O33)4]·50H2O (2), and KNa13H14[(WO2)4(AsW9O33)4]·34H2O (3), were successfully synthesized and thoroughly characterized. Interconversion of structures was accomplished by changing the number of active sites for compounds 1-3. All… read more here.
Keywords: containing polyoxometalates; reaction; coupling reaction; controlled assembly ... See more keywords