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Radical SAM enzymes: Nature's choice for radical reactions

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Published in 2022 at "FEBS Letters"

DOI: 10.1002/1873-3468.14519

Abstract: Enzymes that use a [4Fe‐4S]1+ cluster plus S‐adenosyl‐l‐methionine (SAM) to initiate radical reactions (radical SAM) form the largest enzyme superfamily, with over half a million members across the tree of life. This review summarizes recent… read more here.

Keywords: radical sam; reactions radical; sam; radical reactions ... See more keywords
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Establishing Self‐Dopant Design Principles from Structure–Function Relationships in Self‐n‐Doped Perylene Diimide Organic Semiconductors (Adv. Mater. 42/2022)

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Published in 2022 at "Advanced Materials"

DOI: 10.1002/adma.202204656

Abstract: Self-doping is a particular doping method that has been applied to a wide range of organic semiconductors. However, there is a lack of understanding regarding the relationship between dopant structure and function. We investigated a… read more here.

Keywords: structure function; self dopant; organic semiconductors; doped perylene ... See more keywords
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Polysulfide Catalytic Materials for Fast-Kinetic Metal-Sulfur Batteries: Principles and Active Centers.

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Published in 2021 at "Advanced science"

DOI: 10.1002/advs.202102217

Abstract: Benefiting from the merits of low cost, ultrahigh-energy densities, and environmentally friendliness, metal-sulfur batteries (M-S batteries) have drawn massive attention recently. However, their practical utilization is impeded by the shuttle effect and slow redox process… read more here.

Keywords: sulfur batteries; principles active; polysulfide catalytic; catalytic materials ... See more keywords
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Just‐in‐time clinical video review improves successful placement of Sengstaken‐Blakemore tube by emergency medicine resident physicians: A randomized control simulation‐based study

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Published in 2021 at "AEM Education and Training"

DOI: 10.1002/aet2.10573

Abstract: Successful completion of life‐saving procedures may benefit from a concise just‐in‐time (JIT) intervention. Video is an optimal medium for JIT training, but currently available video‐based references are not optimized for a JIT format, especially in… read more here.

Keywords: video review; medicine; video; blakemore tube ... See more keywords
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Synthesis of novel cyanine dyes as antitumor agents

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Published in 2020 at "Archiv der Pharmazie"

DOI: 10.1002/ardp.202000186

Abstract: In this study, some novel cyanine dyes, 1, 3, and 5−15, were synthesized by a one‐pot step reaction of pyridinium salts 2 and/or 4 with benzenaminium salt 1. N‐{[1‐Chloro‐3,4‐dihydronaphthalen‐2‐yl)methylene]benzenaminium} chloride 1 was obtained by the… read more here.

Keywords: synthesis novel; dyes antitumor; novel cyanine; cyanine dyes ... See more keywords
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Separator Decoration with Cobalt/Nitrogen Codoped Carbon for Highly Efficient Polysulfide Confinement in Lithium-Sulfur Batteries.

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Published in 2017 at "ChemSusChem"

DOI: 10.1002/cssc.201700999

Abstract: A macro-/mesoporous Co-N-C-decorated separator is proposed to confine and reutilize migrating polysulfides. Endowed with a desirable structure and synchronous lithio- and sulfiphilic chemistry, the macro-/mesoporous Co-N-C interface manipulates large polysulfide adsorption uptake, enabling good polysulfide… read more here.

Keywords: macro mesoporous; carbon; separator decoration; polysulfide ... See more keywords
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Three Different Modes of Association between Metal Cations in Heterometallic Uranyl-CoIII and Uranyl-MnII Species

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Published in 2018 at "European Journal of Inorganic Chemistry"

DOI: 10.1002/ejic.201800873

Abstract: Three heterometallic complexes including uranyl and either Co$^{III}$ or Mn$^{II}$ cations were crystallized under hydrothermal conditions. Complexes [Co(bipy)$_3$]$_2$[UO$_2$(NO$_3$)$_4$]$_2$[(UO$_2$)$_2$(NO$_3$)$_4$(OH)$_2$] (1) and [UO$_2$(NO$_3$)$_2$Co(bipy)$_2$(OH)$_2$]·NO$_3$·H$_2$O (2) (bipy = 2,2ʹ‐bipyridine) were obtained from the same solution. UO$_2{^{2+}}$ and Co$^{3+}$ are… read more here.

Keywords: different modes; heterometallic uranyl; hydroxo bridged; metal cations ... See more keywords
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Synthesis of Trimethylolpropane Esters by Base‐Catalyzed Transesterification

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Published in 2020 at "European Journal of Lipid Science and Technology"

DOI: 10.1002/ejlt.201900207

Abstract: Trimethylolpropane (TMP) esters are synthesized from fatty acid methyl esters (FAMEs) and TMP to produce a fluid with properties suitable for use as a lubricant base oil, exhibiting good stability, and low‐temperature performances. In this… read more here.

Keywords: trimethylolpropane esters; base catalyzed; synthesis trimethylolpropane; tmp ... See more keywords
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Tetramethylpyrazine reduces the consequences of nitric oxide inhibition in pregnant rats

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Published in 2019 at "Journal of Cellular Physiology"

DOI: 10.1002/jcp.28579

Abstract: Pre‐eclampsia (PE) is closely associated with perinatal morbidity and mortality and we want to investigate tetramethylpyrazine (TMP)'s effects on PE. Pregnant Sprague–Dawley rats were randomly divided into five groups: normal pregnant (PC), PE, PE+TMP 20 mg/kg,… read more here.

Keywords: tmp inhibited; pregnant rats; inhibition pregnant; name ... See more keywords
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Simultaneous analysis of 6 inorganic anions in urine by double-suppress ion exchange chromatography.

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Published in 2022 at "Journal of separation science"

DOI: 10.1002/jssc.202200106

Abstract: This study is aimed to establish a simple, rapid, and accurate ion chromatography approach for simultaneous detection of 6 inorganic anions in urine. Various performance parameters affecting the determination of anions were optimized, including the… read more here.

Keywords: inorganic anions; anions urine; simultaneous analysis; chromatography ... See more keywords
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Strategic concepts as micro-level tools in strategic sensemaking

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Published in 2018 at "Southern Medical Journal"

DOI: 10.1002/smj.2924

Abstract: Research Summary: The purpose of this article is to illuminate the role of concepts in strategic sensemaking. Based on a longitudinal real‐time study of a city organization, we demonstrate how the concept of “self‐responsibility” played… read more here.

Keywords: concepts micro; strategic sensemaking; micro level; organization ... See more keywords