LAUSR

Ti3C2TX MXene with the merits of metallic conductivity, superhigh volumetric capacitance, and efficient absorption of the electromagnetic wave is considered a promising building block for fiber fabrication; nevertheless, the simultaneous improvement in electrochemical charge storage and electrical conductivity/thermal management is seldom achieved for MXene‐based fibers due to the contradictory in material design. Typically, aligned and densified packing of MXene fibers is highly desired for an enhanced intra‐/inter‐flake electron transport; however, the narrowed inter‐layer spacing restricts the kinetics of ion diffusion (the intercalation/de‐intercalation of electrolyte ions) and diminishes the accessible active sites for charge storage. Herein, the electron and ion transports of Ti3C2TX MXene fiber are synergized via a unique dot‐sheet heterostructure covalently bonded by Ti─C─Ti which provides the optimal inter‐layer spacing for rapid ion diffusion and enhances the intra‐/inter‐flake cross‐linking for fast electron transport. As a result, the obtained fiber offers an improved conductivity of 2405 S cm−1, a desirable capacitance of 1597 F cm−3, an impressive energy density of 19.8 mWh cm−3 for the assembled supercapacitor, superior Joule heating performance, and a photo‐thermal temperature. These remarkable attributes enable their practical applications in energy‐supply scenarios, such as powering LEDs and wearable thermal management.