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Crosslinker-Induced Effects on the Gelation Pathway of a Low Molecular Weight Hydrogel.

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The use of polymeric crosslinkers is an attractive method to modify the mechanical properties of supramolecular materials, but their effects on the self-assembly of the underlying supramolecular polymer networks are… Click to show full abstract

The use of polymeric crosslinkers is an attractive method to modify the mechanical properties of supramolecular materials, but their effects on the self-assembly of the underlying supramolecular polymer networks are poorly understood. Modulation of the gelation pathway of a reaction-coupled low molecular weight hydrogelator is demonstrated using (bio)polymeric crosslinkers of disparate physicochemical identities, providing a handle for control over materials properties.

Keywords: gelation pathway; low molecular; crosslinker induced; induced effects; molecular weight

Journal Title: Advanced materials
Year Published: 2017

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