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A novel wide-gap conjugated polymer PhF2,5 (Eg = 1.9 eV) is designed to contain alternating cyclopentadithiophene and difluorophenylene unit with the goal of favoring unipolar organic field effect transistor characteristics.… Click to show full abstract
A novel wide-gap conjugated polymer PhF2,5 (Eg = 1.9 eV) is designed to contain alternating cyclopentadithiophene and difluorophenylene unit with the goal of favoring unipolar organic field effect transistor characteristics. The higher lowest unoccupied molecular orbital energy of PhF2,5 increases the barrier to electron injection, leading to unipolar transport and higher on/off ratios, without sacrificing desirable high hole mobilities.
Keywords:
mobility electron;
injection properties;
hole mobility;
electron;
electron injection
Journal Title: Advanced materials
Year Published: 2017
Link to full text (if available)
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Journal Title: Advanced materials
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!