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Molecularly Tuned Free Volume of Vapor Cross-Linked 6FDA-Durene/ZIF-71 MMMs for H2 /CO2 Separation at 150 °C.

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The H2 /CO2 separation properties of di/triamine vapor cross-linked mixed matrix membranes with molecularly tuned free-volume at 150 °C are reported. Free-volume is molecularly tuned by altering the degree of… Click to show full abstract

The H2 /CO2 separation properties of di/triamine vapor cross-linked mixed matrix membranes with molecularly tuned free-volume at 150 °C are reported. Free-volume is molecularly tuned by altering the degree of chain-motion using cross-linkers with different chain lengths. A more restricted degree of chain-motion is achieved in the cross-linked network and the resultant membrane has a higher H2 /CO2 selectivity at 150 °C.

Keywords: free volume; cross linked; co2; molecularly tuned

Journal Title: Advanced materials
Year Published: 2017

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