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In Situ Polymer Graphenization Ingrained with Nanoporosity in a Nitrogenous Electrocatalyst Boosting the Performance of Polymer-Electrolyte-Membrane Fuel Cells.

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Rich, porous graphene frameworks decorated with uniformly dispersed active sites are prepared by using polyaniline as a graphene precursor and introducing phenanthroline as a pore-forming agent. The unprecedented fuel-cell performance… Click to show full abstract

Rich, porous graphene frameworks decorated with uniformly dispersed active sites are prepared by using polyaniline as a graphene precursor and introducing phenanthroline as a pore-forming agent. The unprecedented fuel-cell performance of this electrocatalyst is linked to the graphene frameworks with vast distribution of pore sizes, which maximizes the active-sites accessibility, facilitates mass-transport properties, and improves the carbon corrosion resistance.

Keywords: polymer graphenization; electrocatalyst; graphenization ingrained; fuel; performance; situ polymer

Journal Title: Advanced materials
Year Published: 2017

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