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Active Electrochemical Plasmonic Switching on Polyaniline-Coated Gold Nanocrystals.

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High-performance electrochemical plasmonic switching is realized on both single-particle and ensemble levels by coating polyaniline on colloidal gold nanocrystals through surfactant-assisted oxidative polymerization. Under small applied potentials, the core@shell nanostructures… Click to show full abstract

High-performance electrochemical plasmonic switching is realized on both single-particle and ensemble levels by coating polyaniline on colloidal gold nanocrystals through surfactant-assisted oxidative polymerization. Under small applied potentials, the core@shell nanostructures exhibit reversible plasmon shifts as large as 150 nm, a switching time of less than 10 ms, and a high switching stability.

Keywords: plasmonic switching; gold nanocrystals; active electrochemical; electrochemical plasmonic; polyaniline

Journal Title: Advanced materials
Year Published: 2017

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