LAUSR

The demand for portable and wearable chemical or biosensors and their expeditious development in recent years has created a scientific challenge in terms of their continuous powering. As a result, mechanical energy harvesters such as piezoelectric and triboelectric generators (TEGs) have been explored recently either as sensors or harvesters to store charge in small, but long‐life, energy‐storage devices to power the sensors. The use of energy harvesters as sensors is particularly interesting, as with such multifunctional operations it is possible to reduce the number devices needed in a system, which also helps overcome the integration complexities. In this regard, TEGs are promising, particularly for energy autonomous chemical and biological sensors, as they can be developed with a wide variety of materials, and their mechanical energy to electricity conversion can be modulated by various analytes. This review focuses on this interesting dimension of TEGs and presents various self‐powered active chemical and biological sensors. A brief discussion about the development of TEG‐based physical, magnetic, and optical sensors is also included. The influence of environmental factors, various figures of merit, and the significance of TEG design are explained in context with the active sensing. Finally, the key applications, challenges, and future perspective of chemical and biological detection via TEGs are discussed with a view to drive further advances in the field of self‐powered sensors.