LAUSR

Polyaryletherketone (PAEK) is emerging as an important high‐performance polymer material in additive manufacturing (AM) benefiting from its excellent mechanical properties, good biocompatibility, and high‐temperature stability. The distinct advantages of AM facilitate the rapid development of PAEK products with complex customized structures and functionalities, thereby enhancing their applications in various fields. Herein, the recent advances on AM of high‐performance PAEKs are comprehensively reviewed, concerning the materials properties, AM processes, mechanical properties, and potential applications of additively manufactured PAEKs. To begin, an introduction to fundamentals of AM and PAEKs, as well as the advantages of AM of PAEKs is provided. Discussions are then presented on the material properties, AM processes, processing–matter coupling mechanism, thermal conductivity, crystallization characteristics, and microstructures of AM‐processed PAEKs. Thereafter, the mechanical properties and anisotropy of additively manufactured PAEKs are discussed in depth. Their representative applications in biomedical, aerospace, electronics, and other fields are systematically presented. Finally, current challenges and possible solutions are discussed for the future development of high‐performance AM polymers.