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Thermal Transport Properties of Phonons in Halide Perovskites.

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Halide perovskites have emerged as promising candidates for various applications, such as photovoltaic, optoelectronic, and thermoelectric applications. The knowledge of the thermal transport of halide perovskites is essential for enhancing… Click to show full abstract

Halide perovskites have emerged as promising candidates for various applications, such as photovoltaic, optoelectronic, and thermoelectric applications. The knowledge of the thermal transport of halide perovskites is essential for enhancing the device performance for these applications and improving the understanding of heat transport in complicated material systems with atomic disorders. In this work, we review the current understanding of the experimentally and theoretically obtained thermal transport properties of halide perovskites. We comprehensively examine the reported thermal conductivity of methylammonium lead iodide, which is a prototype material, and provide theoretical frameworks for its lattice vibrational properties. The frameworks and discussions are extended to other halide perovskites and derivative structures. The implications for device applications, such as solar cells and thermoelectrics, are discussed. This article is protected by copyright. All rights reserved.

Keywords: properties phonons; transport properties; halide perovskites; transport; thermal transport; phonons halide

Journal Title: Advanced materials
Year Published: 2022

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