High-entropy alloy nanoparticles (HEA-NPs) have attracted great attention because of their unique complex compositions and tailorable properties. Further expanding the compositional space is of great significance for enriching the material… Click to show full abstract
High-entropy alloy nanoparticles (HEA-NPs) have attracted great attention because of their unique complex compositions and tailorable properties. Further expanding the compositional space is of great significance for enriching the material library. Here, we develop a step-alloying strategy to synthesis HEA-NPs containing a range of strongly repellent elements (e.g., Bi-W) by using the Rich-Pt cores formed during the first liquid phase reaction as the seed of the second thermal diffusion. Remarkably, the representative HEA-NPs-(14) with up to 14 elements exhibits extremely excellent multifunctional electrocatalytic performance for pH-universal hydrogen evolution reaction (HER), alkaline methanol oxidation reaction (MOR) and oxygen reduction reaction (ORR). Briefly, HEA-NPs-(14) only requires the ultra-low overpotentials of 11 and 18 mV to deliver 10 mA cm-2 and exhibits ultra-long durability for 400 and 264 hours under 100 mA cm-2 in 0.5 M H2 SO4 and 1 M KOH respectively, which surpasses most advanced pH-universal HER catalysts. Moreover, HEA-NPs-(14) also exhibits an impressive peak current density of 12.6 A mg-1 Pt in 1 M KOH + 1 M MeOH and a half-wave potential of 0.86 V (versus RHE.) in 0.1 M KOH. Our work further expands the spectrum of possible metal alloys, which is important for the broad compositional space and future data-driven material discovery. This article is protected by copyright. All rights reserved.
               
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