LAUSR.org creates dashboard-style pages of related content for over 1.5 million academic articles. Sign Up to like articles & get recommendations!

Highly Stable CsPbX3/PbSO4 Core/Shell Nanocrystals Synthesized by a Simple Post‐Treatment Strategy

Photo by javardh from unsplash

All‐inorganic lead halide perovskite (CsPbX3, X = Cl, Br, I, or their mixture) nanocrystals (NCs) have recently emerged as a promising photoelectric material; however, developing highly stable CsPbX3 NCs still… Click to show full abstract

All‐inorganic lead halide perovskite (CsPbX3, X = Cl, Br, I, or their mixture) nanocrystals (NCs) have recently emerged as a promising photoelectric material; however, developing highly stable CsPbX3 NCs still remains a challenge due to their intrinsic ionic nature. This work presents a simple and facile post‐treatment strategy to encapsulate CsPbX3 NC with PbSO4 nanoshell at single‐particle level. Compared to pristine CsPbX3 NCs, the as‐prepared CsPbX3/PbSO4 NCs exhibit significant enhancement in the optical properties. Benefiting from the efficient protection of inert PbSO4 nanoshell, the obtained CsPbX3/PbSO4 core/shell NCs demonstrate great stability against polar solvents, including ethanol and acetone, and light irradiation. Furthermore, anion‐exchange reaction is strongly restricted upon the encapsulation of PbSO4 shell. This work provides an alternative approach for the synthesis of highly stable CsPbX3 NCs, and paves a new way for the preparation of core/shell heterostructures based on lead halide perovskite NCs.

Keywords: stable cspbx3; cspbx3 pbso4; shell; cspbx3; highly stable; pbso4

Journal Title: Advanced Optical Materials
Year Published: 2020

Link to full text (if available)


Share on Social Media:                               Sign Up to like & get
recommendations!

Related content

More Information              News              Social Media              Video              Recommended



                Click one of the above tabs to view related content.