LAUSR

Thermally stable electron transport (ET) materials with high electron mobility and high triplet state energy level are highly desired for the fabrication of efficient and stable organic light‐emitting diodes (OLEDs). Herein, a new design strategy of constructing through‐space conjugated folded configuration is proposed to explore robust ET materials, opposite to the widely used planar configuration. By bonding two quinolines to the 9,10‐positions of phenanthrene, two novel folded molecules with high thermal and morphological stabilities and high triplet state energy levels (>2.7 eV) are created. These folded molecules possess excellent ET ability with electron mobilities of three orders of magnitude higher than those of linear and planar counterparts. Theoretical calculation and crystallography analysis demonstrate the through‐space conjugated folded configuration has not only reduced reorganization energy but also enlarged charge transfer integral at various dimensions, bringing about efficient multi‐dimensional ET, independent of molecular orientation. By adopting the folded molecule as ET layers, OLEDs with no matter delayed fluorescence or phosphorescence emitters can achieve high external quantum efficiencies and long operational lifetimes simultaneously. This work paves a new avenue towards robust ET materials to improve efficiency and stability of OLEDs.