LAUSR.org creates dashboard-style pages of related content for over 1.5 million academic articles. Sign Up to like articles & get recommendations!

Pushing the Efficiency of High Open‐Circuit Voltage Binary Organic Solar Cells by Vertical Morphology Tuning

Photo from wikipedia

The tuning of vertical morphology is critical and challenging for organic solar cells (OSCs). In this work, a high open‐circuit voltage (VOC) binary D18‐Cl/L8‐BO system is attained while maintaining the… Click to show full abstract

The tuning of vertical morphology is critical and challenging for organic solar cells (OSCs). In this work, a high open‐circuit voltage (VOC) binary D18‐Cl/L8‐BO system is attained while maintaining the high short‐circuit current (JSC) and fill factor (FF) by employing 1,4‐diiodobenzene (DIB), a volatile solid additive. It is suggested that DIB can act as a linker between donor or/and acceptor molecules, which significantly modifies the active layer morphology. The overall crystalline packing of the donor and acceptor is enhanced, and the vertical domain sizes of phase separation are significantly decreased. All these morphological changes contribute to exciton dissociation, charge transport, and collection. Therefore, the best‐performing device exhibits an efficiency of 18.7% with a VOC of 0.922 V, a JSC of 26.6 mA cm−2, and an FF of 75.6%. As far as it is known, the VOC achieved here is by far the highest among the reported OSCs with efficiencies over 17%. This work demonstrates the high competence of solid additives with two iodine atoms to tune the morphology, particularly in the vertical direction, which can become a promising direction for future optimization of OSCs.

Keywords: organic solar; circuit; morphology; solar cells; vertical morphology; high open

Journal Title: Advanced Science
Year Published: 2022

Link to full text (if available)


Share on Social Media:                               Sign Up to like & get
recommendations!

Related content

More Information              News              Social Media              Video              Recommended



                Click one of the above tabs to view related content.