LAUSR

With the characteristics of low driving voltage, light weight, and flexibility, ionic polymer‐metal composites (IPMCs) have attracted much attention as excellent candidates for artificial muscle materials in the fields of biomedical devices, flexible robots, and microelectromechanical systems. Under small voltage excitation, ions inside the IPMC proton exchange membrane migrate directionally, leading to differences in the expansion rate of the cathode and the anode, which in turn deform. This behavior is caused by the synergistic action of a three‐layer structure consisting of an external electrode layer and an internal proton exchange membrane, but the electrode layer is more dominant in this process due to the migration and storage of ions. The exploration of modifications and alternatives for proton exchange membranes and recent advances in the fabrication and characterization of conductive materials, especially carbon‐based materials and conductive polymers, have contributed significantly to the development of IPMCs. This paper reviews the progress in the application of proton exchange membranes and electrode materials for IPMCs, discusses various processes currently applied to IPMCs preparation, and introduces various promising applications of cutting‐edge IPMCs with high performance to provide new ideas and approaches for the research of new generation of low‐voltage ionic soft actuators.