LAUSR

The application of membrane‐based separation processes for propylene/propane (C3H6/C3H8) is extremely promising and attractive as it is poised to reduce the high operation cost of the established low temperature distillation process, but major challenges remain in achieving high gas selectivity/permeability and long‐term membrane stability. Herein, a C3H6 facilitated transport membrane using trisilver pyrazolate (Ag3pz3) as a carrier filler is reported, which is uniformly dispersed in a polymer of intrinsic microporosity (PIM‐1) matrix at the molecular level (≈15 nm), verified by several analytical techniques, including 3D‐reconstructed focused ion beam scanning electron microscropy (FIB–SEM) tomography. The π‐acidic Ag3pz3 combines preferentially with π‐basic C3H6, which is confirmed by density functional theory calculations showing that the silver ions in Ag3pz3 form a reversible π complex with C3H6, endowing the membranes with superior C3H6 affinity. The resulting membranes exhibit superior stability, C3H6/C3H8 selectivity as high as ≈200 and excellent C3H6 permeability of 306 Barrer, surpassing the upper bound selectivity/permeability performance line of polymeric membranes. This work provides a conceptually new approach of using coordinatively unsaturated 0D complexes as fillers in mixed matrix membranes, which can accomplish olefin/alkane separation with high performance.