LAUSR

A possible strategy to give a simultaneous boost to the energy and power attributes of the current generation of lithium‐ion batteries is developing thick porous electrodes with a high loading of active material alongside optimal percolation networks for the ions and electrons. However high the insertion capacity and kinetics of the single particle lithium‐insertion materials, the energy and power density of the cell can be capped by the ionic and electronic transport limitations in the porous electrode. In this work, a physical picture grounded in experiment and theory is proposed to spotlight and quantify the pivotal role of the micro‐scale porosity and active‐material loading in determining the tortuosity, effective transport properties, and performance limitations of porous electrodes. The outcome is a phenomenological picture coupled with a theoretical framework for the deconvolution of the relative shares of the electronic and ionic transport limitations over short and long ranges regarding the performance limitation of lithium‐ion batteries.