LAUSR

H2 chemisorption measurements are used to estimate the size of supported metal particles, often using a hydrogen-tosurface-metal stoichiometry of unity. This technique is most useful for small particles whose sizes are difficult to estimate through electron microscopy or X-ray diffraction. Undercoordinated metal atoms at the edges and corners of particles, however, make up large fractions of small metal clusters, and can accommodate multiple hydrogen atoms leading to coverages which exceed 1 ML (supra-monolayer). Density functional theory was used to calculate hydrogen adsorption energies on Pt and Ir particles (38–586 atoms, 0.8–2.4 nm) at high coverages ( 3.63 ML). Calculated differential binding energies confirm that Pt and Ir (111) single-crystal surfaces saturate at 1 ML; however, Pt and Ir clusters saturate at supra-monolayer coverages as large as 2.9 ML. Correlations between particle size and saturation coverage are provided that improve particle size estimates from H2 chemisorption for Pt-group metals. VC 2018 American Institute of Chemical Engineers AIChE J, 00: 000–000, 2018