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Gold(I)‐catalyzed Synthesis of Axially Chiral Indolo[2,3‐c]carbazole Exhibiting Advanced Electrochromic Response

The Wurster’s Blue skeleton embedded in an axially chiral indolo[2,3‐c]carbazole framework can act as a key chromophore to realize three‐way‐output electrochromic response (UV‐Vis‐near IR absorption, fluorescence, and circular dichroism) upon… Click to show full abstract

The Wurster’s Blue skeleton embedded in an axially chiral indolo[2,3‐c]carbazole framework can act as a key chromophore to realize three‐way‐output electrochromic response (UV‐Vis‐near IR absorption, fluorescence, and circular dichroism) upon reversible electrochemical interconversion with the corresponding neutral electron donor, which was effectively synthesized by gold(I)‐catalyzed cascade cyclization of 2‐azidophenyl‐1,3‐butadiyne with a 2‐phenyl‐1‐naphthyl terminal group.

Keywords: indolo carbazole; axially chiral; chiral indolo; gold catalyzed; electrochromic response

Journal Title: Asian Journal of Organic Chemistry
Year Published: 2025

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