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Eight heteroleptic palladium complexes containing both N-heterocyclic carbenes and NH-heterocycle azoles (pyrazole and indazole) were synthesized and characterized, and their structures were unambiguously confirmed using single-crystal X-ray diffraction. Further investigation… Click to show full abstract
Eight heteroleptic palladium complexes containing both N-heterocyclic carbenes and NH-heterocycle azoles (pyrazole and indazole) were synthesized and characterized, and their structures were unambiguously confirmed using single-crystal X-ray diffraction. Further investigation of the complexes as catalysts in the Suzuki–Miyaura reaction and Buchwald–Hartwig amination revealed good reactivities for aryl chlorides.
Keywords:
heteroleptic heterocyclic;
indazole complexes;
complexes synthesis;
carbene pyrazole;
pyrazole indazole;
heterocyclic carbene
Journal Title: Applied Organometallic Chemistry
Year Published: 2017
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Journal Title: Applied Organometallic Chemistry
Year Published: 2017
Link to full text (if available)
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recommendations!