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Synthesis of nanomagnetic supported thiourea–copper(I) catalyst and its application in the synthesis of triazoles and benzamides

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A novel nanomagnetic supported thioureaâ��copper(I) complex and inorganicâ��organic Takemoto-like hybrid nanomagnetic catalyst was designed, and synthesized. The prepared naomagnetic catalyst was characterized using Fourier transform infrared spectroscopy, X-ray diffraction, energy-dispersive… Click to show full abstract

A novel nanomagnetic supported thiourea�copper(I) complex and inorganic�organic Takemoto-like hybrid nanomagnetic catalyst was designed, and synthesized. The prepared naomagnetic catalyst was characterized using Fourier transform infrared spectroscopy, X-ray diffraction, energy-dispersive X-ray analysis, transmission and scanning electron microscopies, thermogravimetry, nitrogen adsorption/desorption, zeta potential and vibrating sample magnetometry. Furthermore, the fabricated dual-role inorganic�organic hybrid catalyst shows a striking and robust catalytic activity for the synthesis of triazoles and benzamides through click and coupling reactions, respectively, under mild and eco-friendly reaction conditions. Copyright © 2017 John Wiley & Sons, Ltd.

Keywords: synthesis triazoles; synthesis; supported thiourea; nanomagnetic supported; catalyst; thiourea copper

Journal Title: Applied Organometallic Chemistry
Year Published: 2018

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