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Fe3O4@SiO2–ZrCl2‐MNPs: A novel magnetic catalyst for the clean and efficient cascade synthesis of 1‐(benzothiazolylamino)methyl‐2‐naphthol derivatives in the absence of solvent

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A green, simple and eco-friendly three-component condensation for the synthesis of 1-(benzothiazolylamino)methyl-2-naphthols using new magnetic nanoparticles formulated as Fe3O4@SiO2–ZrCl2-MNPs is described. Considering the economic and environmental aspects, the method provides… Click to show full abstract

A green, simple and eco-friendly three-component condensation for the synthesis of 1-(benzothiazolylamino)methyl-2-naphthols using new magnetic nanoparticles formulated as Fe3O4@SiO2–ZrCl2-MNPs is described. Considering the economic and environmental aspects, the method provides some advantages such as clean procedure, solvent-free conditions, simple operation and work-up, relatively short reaction times and high yields of the products. Moreover the introduced catalyst can be readily recovered up to 4 consecutive runs with consistent activity using an external magnet.

Keywords: sio2 zrcl2; fe3o4 sio2; synthesis benzothiazolylamino; zrcl2 mnps; benzothiazolylamino methyl

Journal Title: Applied Organometallic Chemistry
Year Published: 2018

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