LAUSR

Triple-shape-memory polymers are capable of memorizing two temporary shapes and sequentially recovering from the first temporary shape to the second temporary shape and eventually to the permanent shape upon exposure to a stimulus. In this study, unique three-component, multilayered films with an ATBTA configuration [where A is polyurethane (PU), B is ethylene vinyl acetate (EVA), and T is poly(vinyl acetate) (PVAc)] were produced as a triple-shape-memory material via a forced-assembly multilayer film coextrusion process from PU, EVA, and PVAc. The two well-separated thermal transitions of the PU–EVA–PVAc film, the melting temperature of EVA and the glass-transition temperature of PVAc, allow for the fixing of the two temporary shapes. The cyclic thermomechanical testing results confirm that the 257-layered PU–EVA–PVAc films possessed outstanding triple-shape-memory performance in terms of the shape fixity and shape-recovery ratios. This approach allowed greater design flexibility and simultaneous adjustment of the mechanical and shape-memory properties. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 44405.