LAUSR

Establishment of high‐performance epoxy resin with satisfactory fire safety, mechanical properties, and excellent transparency is urgently desirable, but still remains significant challenges. Herein, a super‐tough yet high flame retardant epoxy resin (EP/BTD) was designed and prepared by incorporating bi‐DOPO structure and hydrogen‐bonding networks. Although the phosphorus content was only 0.69 wt% (10 wt% of bi‐DOPO flame retardant [BTD]), EP/BTD‐10 showed a high limiting oxygen index value (33.4%), satisfactory UL‐94 rating (V‐0), and good heat suppression ability (total heat release [THR] and peak heat release rate [PHRR] reduced to 29.0% and 42.2%, respectively). Furthermore, the flame retardant mechanism of EP/BTD was illustrated and attributed to dual‐phase fire‐retardant effect. Additionally, EP/BTD‐7.5 featured notably mechanical properties, of which the tensile strength, elongation at break and impact strength increased by 44.6%, 40.0%, and 232.6%, respectively, due to hydrogen‐bonding network and π–π interaction. More importantly, EP/BTD maintained high visible light transmittance and excellent UV‐blocking properties. In summary, this work provided a guidance for the development of high‐performance epoxy resin and was expected to expand the practical applications.