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A photochemoenzymatic halodecarboxylation of ferulic acid was achieved using vanadate‐dependent chloroperoxidase as (bio)catalyst and oxygen and organic solvent as sole stoichiometric reagents in a biphasic system. Performance and selectivity were… Click to show full abstract
A photochemoenzymatic halodecarboxylation of ferulic acid was achieved using vanadate‐dependent chloroperoxidase as (bio)catalyst and oxygen and organic solvent as sole stoichiometric reagents in a biphasic system. Performance and selectivity were improved through a phase transfer catalyst, reaching a turnover number of 660.000 for the enzyme.
Keywords:
halodecarboxylation ferulic;
ferulic acid;
borodin type;
hunsdiecker borodin;
photochemoenzymatic hunsdiecker
Journal Title: Chembiochem
Year Published: 2022
Link to full text (if available)
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Journal Title: Chembiochem
Year Published: 2022
Link to full text (if available)
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recommendations!