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Coke‐Tolerant Gadolinium‐Promoted HZSM‐5 Catalyst for Methanol Conversion into Hydrocarbons

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The role of Gd as a coke inhibitor was studied for the methanol‐to‐hydrocarbons reaction. It was revealed that thin films of gadolinium oxide covered the ZSM‐5 crystals and that the… Click to show full abstract

The role of Gd as a coke inhibitor was studied for the methanol‐to‐hydrocarbons reaction. It was revealed that thin films of gadolinium oxide covered the ZSM‐5 crystals and that the Gd atoms that were uniformly dispersed on the surface enhanced the basicity of the parent ZSM‐5. These synergetic effects improved the durability of the acidic function and diminished the growth of coke precursors, which resulted in an increased lifetime of the catalyst.

Keywords: gadolinium promoted; tolerant gadolinium; promoted hzsm; catalyst; coke tolerant; gadolinium

Journal Title: ChemCatChem
Year Published: 2017

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