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Cyclopentadienone iron dicarbonyl complexes were applied in the alkylation of ketones with various aliphatic and aromatic ketones and alcohols via the borrowing hydrogen strategy in mild reaction conditions. DFT calculations… Click to show full abstract
Cyclopentadienone iron dicarbonyl complexes were applied in the alkylation of ketones with various aliphatic and aromatic ketones and alcohols via the borrowing hydrogen strategy in mild reaction conditions. DFT calculations and experimental works highlight the role of the transition metal Lewis pairs and the base. These iron complexes demonstrated a broad applicability in mild conditions and extended the scope of substrates.
Keywords:
alkylation ketones;
ketones catalyzed;
catalyzed bifunctional;
iron;
iron complexes
Journal Title: ChemCatChem
Year Published: 2017
Link to full text (if available)
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Journal Title: ChemCatChem
Year Published: 2017
Link to full text (if available)
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recommendations!