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A series of well‐defined copper(I) complexes bearing ring‐expanded N‐heterocyclic carbene (NHC) ligands has been applied to the azide–alkyne cycloaddition reaction. The obtained results notably showed that the six‐membered NHC ligands… Click to show full abstract
A series of well‐defined copper(I) complexes bearing ring‐expanded N‐heterocyclic carbene (NHC) ligands has been applied to the azide–alkyne cycloaddition reaction. The obtained results notably showed that the six‐membered NHC ligands outperform well‐established five‐membered ones. [CuI(Mes‐6)] displayed a remarkable catalytic activity while respecting the strict criteria for click reactions.
Keywords:
heterocyclic carbenes;
cycloaddition;
copper;
azide alkyne;
expanded heterocyclic;
ring expanded
Journal Title: Chemcatchem
Year Published: 2018
Link to full text (if available)
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Journal Title: Chemcatchem
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!