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Herein, we introduce a new class of bench‐stable N‐heterocyclic carbene (NHC) nickel‐precatalysts for homogeneous nickel‐catalysis. The nickel(II) complexes are readily activated to Ni0 in situ under mild conditions, via a proposed… Click to show full abstract
Herein, we introduce a new class of bench‐stable N‐heterocyclic carbene (NHC) nickel‐precatalysts for homogeneous nickel‐catalysis. The nickel(II) complexes are readily activated to Ni0 in situ under mild conditions, via a proposed Heck‐type mechanism. The precatalysts are shown to facilitate carbonyl‐ene, hydroalkenylation, and amination reactions.
Keywords:
stable heterocyclic;
bench stable;
carbene nickel;
nickel precatalysts;
heterocyclic carbene
Journal Title: Chemcatchem
Year Published: 2018
Link to full text (if available)
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Journal Title: Chemcatchem
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!