Photo by candid from unsplash
The first ortho‐alkenylation of aromatic amidines with alkynes was realized by earth‐abundant manganese catalysis through C−H activation. A catalytic amount of PhMgBr was found essential for improved efficiency of this… Click to show full abstract
The first ortho‐alkenylation of aromatic amidines with alkynes was realized by earth‐abundant manganese catalysis through C−H activation. A catalytic amount of PhMgBr was found essential for improved efficiency of this transformation. Wide tolerance of functional groups and excellent E/Z selectivity highlighted the current protocol.
Keywords:
aromatic amidines;
ortho alkenylation;
amidines alkynes;
activation;
alkenylation aromatic
Journal Title: ChemCatChem
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: ChemCatChem
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!