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Abstract: Supported Pd nanoparticles catalyzed the reductive cycloisomerization of diynes to give 1,3‐dienes, and subsequent intermolecular [4+2] cycloaddition with dienophiles led to cyclohexene derivatives. Various diynes and dienophiles participated in… Click to show full abstract
Abstract: Supported Pd nanoparticles catalyzed the reductive cycloisomerization of diynes to give 1,3‐dienes, and subsequent intermolecular [4+2] cycloaddition with dienophiles led to cyclohexene derivatives. Various diynes and dienophiles participated in the one‐pot reaction to give the corresponding products in good to high yields. Al2O3‐supported Pd catalysts were highly tolerant toward air and reusable.
Keywords:
cycloisomerization diynes;
reductive cycloisomerization;
cycloaddition;
one pot
Journal Title: ChemCatChem
Year Published: 2019
Link to full text (if available)
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Journal Title: ChemCatChem
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!