Photo by kolyakorzh from unsplash
Hydrogenations have been dominated by transition metal catalysis, while the use of more abundant and inexpensive main group metal catalysts has remained a great challenge. Here, a bimetallic Li/Al dihydride… Click to show full abstract
Hydrogenations have been dominated by transition metal catalysis, while the use of more abundant and inexpensive main group metal catalysts has remained a great challenge. Here, a bimetallic Li/Al dihydride was successfully applied to catalytic hydrogenations of imines. The catalyst [(DippBIAN)Al(μ‐H)2Li(OEt2)2] was easily prepared from the 2e‐reduced BIAN derivative and LiAlH4.
Keywords:
imine hydrogenation;
catalysed imine;
bian aluminium;
aluminium catalysed
Journal Title: Chemcatchem
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Chemcatchem
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!