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Three Cu(I) complexes derived from stereodynamic diphosphine ligands were synthesized and used for chirality sensing. The coordination of diamines and amino acids to these complexes generates distinct circular dichroism signals.… Click to show full abstract
Three Cu(I) complexes derived from stereodynamic diphosphine ligands were synthesized and used for chirality sensing. The coordination of diamines and amino acids to these complexes generates distinct circular dichroism signals. The chiroptical sensor response allows determination of the absolute configuration and the enantiomeric excess of the analyte at low concentrations. This method is operationally simple, fast, and attractive for high-throughput sensing applications.
Keywords:
copper complexes;
chirality;
chirality sensing;
stereodynamic copper;
sensing stereodynamic
Journal Title: Chirality
Year Published: 2017
Link to full text (if available)
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Journal Title: Chirality
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!