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An Azulene-Fused Tetracene Diimide with a Small HOMO-LUMO Gap.

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A newly prepared tetraazulene-fused tetracene diimide (TA-fused TDI) showed absorption in the near-IR region owing to the effective extension of the π-conjugated system as well as a large two-photon absorption… Click to show full abstract

A newly prepared tetraazulene-fused tetracene diimide (TA-fused TDI) showed absorption in the near-IR region owing to the effective extension of the π-conjugated system as well as a large two-photon absorption cross-section (σ(2) =2140 GM) at 950 nm. Four reversible reduction processes and n-type semiconductivity were also confirmed as attractive electronic properties of this compound.

Keywords: small homo; azulene fused; fused tetracene; homo lumo; tetracene diimide; diimide small

Journal Title: ChemPlusChem
Year Published: 2017

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