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Hydrothermal Synthesis of Znx Ni1-x S Nanosheets for Hybrid Supercapacitor Applications.

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Nickel-foam-supported Znx Ni1-x S nanosheets are synthesized by a two-step hydrothermal method. The Znx Ni1-x S nanosheets can be considered as the product of the partial substitution of Zn2+ ions… Click to show full abstract

Nickel-foam-supported Znx Ni1-x S nanosheets are synthesized by a two-step hydrothermal method. The Znx Ni1-x S nanosheets can be considered as the product of the partial substitution of Zn2+ ions by Ni2+ ions in the ZnS lattice. The resulting Znx Ni1-x S/Ni foam can be directly used as an electrode for supercapacitors. It can reach a specific capacitance of 1412 F g-1 at a current density of 1 Ag-1 with 68.0 % capacitance retention at 16 Ag-1 . Control experiments show that the electrochemical performances of Znx Ni1-x S nanosheets are much better than those of ZnS and NiS prepared under the same conditions. Furthermore, a hybrid supercapacitor device was assembled by using the Znx Ni1-x S nanosheets as the positive electrode and porous carbon as the negative electrode; the device exhibited high power and energy densities. This study demonstrates that the construction of bimetal sulfides is a strategy to develop high-performance supercapacitor electrode materials.

Keywords: hybrid supercapacitor; hydrothermal synthesis; znx ni1; ni1 nanosheets

Journal Title: ChemPlusChem
Year Published: 2017

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